Showing posts with label orbital angular momentum of atom. Show all posts
Showing posts with label orbital angular momentum of atom. Show all posts

Wednesday, February 8, 2012

Hermitian Matrices and Orbital Angular Momentum

We continue now with further examples of how Hermitian matrices and operators play a role in advanced physics. Of some use for the interested reader will be two previous blogs in which the concept of orbital angular momentum at the quantum-atomic level was introduced, including examples of problems based on it. See e.g.
http://brane-space.blogspot.com/2010/07/space-quantization-further-simple-qm.html

and

http://brane-space.blogspot.com/2010/07/solution-of-quantum-mechanics-problems.html

For example, we can look at the orbital angular momentum vectors in the x and y -directions, given by L(x) and L(y). Since these are Hermitian, i.e.

L(x) = h/2π [σ_x ] = ħ [σ_x ] , and L(y) = h/2π [σ_y ] = ħ [σ_y ]

where ħ = h/2π and σ_x, σ_y are the Pauli spin matrices as given in the earlier blog, viz.

http://brane-space.blogspot.com/2012/02/uses-of-hermitian-matrices-in-physics.html

and h is the Planck constant (h = 6.62 x 10^-34 J-sec), then it follows that the forms:

(L(x) + i L(y)) and (L(x) - i L(y)) are Hermitan conjugates.

These mathematical facts can be used to obtain expressions in terms of the quantum numbers l and m (see the first two blog links), where we solve for the quantity ‖C^m‖:

‖C^m‖ = ħ [(l - m) (l + m + 1)]^½

To determine the allowed values of l and m one always begins with the fact that if one is given a wave function, U (m,l) one can always generate a wave function U(m+1), l or U(m-1),l by operating respectively with (L(x) + i L(y)) or (L(x) - i L(y)). If m and m' then refer to spin quantum numbers in columns and row rspectively and d references diagonals, then:

(L(x) + i L(y)) m.m' = ħ [(l - m') (l + m' + 1)]^½ dm,m'+1

and

(L(x) - i L(y)) m.m' = ħ [(l - m) (l + m + 1)]^½ dm',m+1

The case of l = ½ is especially easy to treat and we get:

(L(x) + i L(y)) m.m' = ħ [(½ - m') (½ + m' + 1)]^½ dm,m'+1

= ħ x

(0...1)
(0....0)

and:

(L(x) - i L(y)) m.m' = ħ [(½ - m) (l½ + m + 1)]^½ dm',m+1

= ħ x

(0...0)
(1....0)

Problems:

1) Solve for σ_x, σ_y and σ_z in terms of the orbital angular momenta, L(x), L(y) and L(z)

2) Solve for the spin-momentum operators s(x), s(y) and s(z) in terms of σ_x, σ_y and σ_z. (State any assumptions made)

3) Show that the TOTAL angular momentum vector, J(z) =

(ħ/i (@/@φ )+ ħ/2 ..... 0)

(0 ....... ħ/i (@/@ φ ) - ħ/2)

displays a Hermitian matrix, where φ is a spherical angle and @/@ φ denotes a partial derivative with respect to it.

4) Show by direct computation that:

σ_x σ_y + σ_y σ_z =

(i……….i)
(i………-i)

5) Compute the matrices for (L(x) + i L(y)) m.m' and (L(x) - i L(y)) m.m' if the angular momentum quantum number l = -1.