Showing posts with label ethane. Show all posts
Showing posts with label ethane. Show all posts

Friday, October 25, 2019

How Fracking Drives The Proliferation of Plastics & Ocean Pollution, Acidification

A drilling rig operates in Erie in 2015.
Fracking operation in Colorado and a seal pup partially strangled by plastics.

   Humans produce roughly our own weight in plastics each year. How much actually ends up in the oceans is still a matter of debate but scientists in one study have estimated between 4.8 and 12.7  million metric tonnes (in 2010 alone).   Three- fourths of the plastic waste on Earth comes from uncollected litter,  the  leaked from assorted dump sites over the years.  Most of the drastic increase between 1950  and 2015  has been documented in the Journal  Science Advances, i.e.

https://www.researchgate.net/publication/318567844_Production_use_and_fate_of_all_plastics_ever_made

We're now much more aware of how the fracking process is powering a dangerous plastics bonanza,  with the plastics and fracking industries working hand-in-hand to prop up their respective pollution models.   Basically, the fracking industry requires a new source  for yearly demand to sop up its excess gas.  This is to justify more drilling while the plastics industry needs a new source of  low -cost ethane, a fracking byproduct used to manufacture plastics.  As I showed in a previous post, much of this  plastic refuse ends up in our oceans threatening sea life as well as humans - both  ingesting vastly more micro-plastics than ever before.

Apart from that micro-plastics impact, bear in mind  the role of the industrial plants that convert natural gas into petrochemicals emit massive amounts of air and climate pollutants - including carbon dioxide (CO2).  When rising levels of the gas are absorbed in the oceans it exacerbates ocean acidification, i.e. based on the chemical reaction:  CO2  +  H2O ->   H2CO 3

Where H2CO3 is carbonic acid.

How was this produced?  Well, the rapid expansion of fracking created a natural gas glut that drove actual gas prices to the lowest levels in decades.  The plastics industry then rode to the rescue of the gas frackers.  According to Plastics News: "Fracking represents a once -in -a generation opportunity for the plastics industry".   At the same time, a renewed push for plastics manufacturing provides the frackers with a polluting partner to absorb the ever increasing quantity of fracked gas (e.g. methane, much of which is already allowed to be burned off in situ, thanks to altered regulations by the Trumpites.)

It's no surprise then that Wall Street's greedy investors are lining up to build new factories that transform fracking byproducts into plastics. They see more profits pouring in - to pad their bottom lines- but are blind to the toxins pumped out to defile the environment and ruin public health. So now, not only is fracking polluting our air, soil and water, it's also directly affecting the oceans - which harbor the greatest oxygen source on the planet in the form of plankton.

Let's also process  - from the industry's own projections  -   that the global plastics industry is expected to increase production by 40 percent over the next decade.  This is driven by dropping prices for fracking byproducts as well as massively scaled -up production.   This is given that most of the  industry manufactures packaging materials that are immediately discarded.

For perspective, each human on average (globally) disposes of 110 pounds of plastic annually. Process that! It's the weight of a small frame woman.  Much of this ends up in the oceans where it strangles the resident sea life (like sea lions) or ends up accumulating in their stomachs causing them to die of starvation.

Since 1950, the  plastics industry - which had its major shout out in the 1967 film 'The Graduate' ("One word for you, Ben: Plastics!") -   has produced 18.3 trillion pounds of plastics, of which only about 9 percent has been recycled.   That translates into 16 trillion pounds tossed into landfills of which a significant proportion  (30 %) ends up in the oceans.

Less  well known:  Plastic products are inherently toxic and can become a vehicle for other pollutants. Many plastics contain hazardous chemicals and thousands of different additives, which can leach out as the plastic ages.  Such additives can comprise up to half of the object's  weight and be extremely toxic - including endocrine disrupters which affect hormone function.

Once created,  plastics can last for hundreds to thousands of years and the toxic remains of plastics pose serious challenges.   Meanwhile, the microplastics are ubiquitous, finding their way into the food we eat, soil and air we breath. Even indoor air can have high concentrations of microplastics from household products and synthetic textiles. 

We are basically awash in plastics, microplastics even as the fracking industry is making the situation much worse.

Let us also dispel (for the last time)  the cockeyed notion that natural gas is a "clean" fuel source. While it might be "clean" relative to the tar sands oil from the Keystone pipeline, it's not in any way clean standing on its own.  It is another fossil fuel - cheap but still dirty  -  and if you doubt it ask the homeowners who have frack wells near their homes in the Colorado suburbs.  See, for example, this item which greeted us in today's news paper:
Image may contain: possible text that says 'OIL AND GAS STUDY RAISES CONCERN state-funded study of emissions from oil and gas development found the chemicals, including benzene and pose risks to human health. While the study did not measure actual health effects for people who live close to oil and gas operations, it used modeling to predict how pol- lutants would move the air. Researchers found that people who lived far 2,000 feet away from a well pad could face health effects including headaches, dizziness and respiratory problems.'

The conclusion is self-evident: Rather than investing in fossil fuels and their ancillary chemical industry we need to invest more in renewable energy, including solar, geothermal, wind.

Friday, February 2, 2018

If Pluto Has Clouds Can It Still Be A "Dwarf Planet"?

Pluto-clouds
A sequence of images taken by the Long Range Reconnaissance Imager and Multispectral Visible Imaging Camera from the New Horizons spacecraft Pluto flyby  in July, 2015. The images show possible evidence for clouds on Pluto but altitude data are needed to confirm this.

Alan Stern, New Horizons principal investigator,  gave a terrific analogy to the demotion of Pluto to a 'dwarf planet' in the NOVA special  'Chasing Pluto'.  He compared the ridiculous IAU vote (to decide Pluto was a "dwarf" as opposed to "real" planet)  to a similar vote by canine specialists to vote all small dogs, i.e. pugs, Chihuahuas etc. to 'dwarf dogs' while all larger dogs are 'real dogs'.   

Stern has been consistent in his position that Pluto is emphatically a genuine planet , never mind the contrived definition offered by some (e.g. Michael Brown).  Stern maintains Pluto is a planet simply because it is massive enough that gravity has forced it into a spherical shape.

Now it appears there is even further physical evidence -  from the New Horizons mission - that this dwarf planet nonsense might finally be put to rest. And who might we thank other than the same Alan Stern who has described several lines of evidence that Pluto may exhibit partly cloudy skies.  Can such clouds be an attribute of a dwarf planet? I doubt it, for the same reason that it is unlikely a genuine dwarf world would have adequate gravity to force it into a spherical shape.  Bottom line:  a dwarf world wouldn't have the gravity to retain any kind of atmosphere, it would be outgassed.  We can use:

v =  Ö( (3 k T/m)

where k is Boltzmann's constant (1.38 x 10 -23   J/K), T is the absolute temperature applicable in degrees K, and m is the mass of the most prominent, constituent single gas  molecule . We then compare this value to the escape velocity of the object.

Anyway, Stern's new findings were presented on October 18 last year to a joint meeting of the American Astronomical Society Division for Planetary Sciences and European Planetary Sciences Congress.  This took place in Pasadena, California and interested readers can find more details at:   

http://bit.ly/aas-dps

Let's note that previous observations have shown that Pluto does have a hazy atmosphere. This arises as a result of a process involving sunlight (even at that great distance) and hydrocarbons present. In particular, when sunlight strikes the planet it triggers formation of the haze composed of hydrocarbons like acetylene and ethane.  These chemicals then coagulate into small particles that scatter sunlight - visible as a blue mist captured in the images captured by the instruments aboard the New Horizon.

This haze, to be sure, is extremely thin whereas the particles of vapor that meteorologists would classify as clouds must be discrete, optically thick objects that block the surface.. So again, we have to deal with some scientific semantics here.

How to reconcile the Earth meteorologists' definition with what Stern's New Horizons team found? Well, the latter actually spotted - using the instruments cited- several bright smudges at apparently low altitudes that blocked Pluto's surface. (Refer to the last two images on the right of the top panel). These appeared at Pluto's dawn and dusk when lower temperatures would allow condensed clouds to form.

Moreover, the Stern team spotted these features at low altitudes which totally conforms with what a planetary atmospheric model of cloud formation would expect to yield.

The bugbear or the primary obstacle preventing a definite confirmation?  Because the Stern team lacks altitude data they can't yet confirm whether the features detected optically hang above Pluto's surface  or lie atop it. Once we get that resolved then a more unambiguous conclusion is possible.

For my part - and Stern's (who's articulated this before) we don't need the cloud confirmation to ascertain Pluto is definitely a planet - and not a mere "dwarf" planet.

In Stern's Wall Street Journal interview (July 18-19, 2015 p. A9) he addressed the admission of one IAU voter to vote for Pluto being a dwarf planet. To wit,  "We're not so keen to have Pluto and all his friends in the club because it gets crowded. By the end of the decade we would have had 100 planets.."

Hmmm...can't have too many planets, eh?, Otherwise they'd all have to be named and the poor little school kids wouldn't be able to remember them all.  Stern's response (ibid.):

"That's a very 20th century view. Our technology used to be very limited, so we could only see a few planets, and we could memorize the list because we thought we knew them all. Arbitrarily limiting the number of planets to a familiar few is like deciding to name only seven mountains on Earth,"

Of course, one response of the pro-dwarfers would be that gazillions of people are more interested in space and the planets rather than all the terrestrial mountains. But in fact that planet -space prejudice is immaterial to Stern's basic point. In another parallel universe, many more might be interested in mountains... but planets -  not so much.


Another type of objector who might brainlessly ask: "Why does it matter if we call Pluto a planet?  Only a bean counter might care"

However, we do care because scientific terminology has consequences. It's not a mere casual parlor game of semantics. It matters because scientific methods and processes are important, not because "a name by any other name" means anything....to anyone.  If people (laymen) perceive that planetary status (which ought to be an OBJECTIVE finding) is accomplished by subjective vote, then you really can't blame them for buying into the agnotology message- i.e. hat consensus, i.e. in the anthropogenic warming setting, means science is decided by popularity.

And more importantly, if scientific words and terms meaning nothing and are all relative, that opens the door to direct exploitation by ideology and  authoritarians who'd like to play upon the fake news idiom. This we cannot afford.   As one blog commenter Laurel  Kornfield put it:

"Clearly, more than "a few bean counters" care about what we call Pluto, and this is a good thing. It means they are paying attention to astronomy and have the discretion to distinguish a poor definition from a good one. "


Would it be nice and seal the deal to learn Pluto has a bona fide atmosphere? Sure, but in the end it is not necessary for regarding Pluto as a bona fide planet - as opposed to a dwarf planet.

See also Laurel's blog at:

http://laurele.livejournal.com